The tubing has never been exposed to direct sunlight since the slab was pored 20 years ago. So I'd expect no degradation at all. My brother sealed the tubes with the manifolds installed and nothing in the floor zones, no air or water, its all been covered and not exposed for 20 years. So assuming no tubing failures and nothing getting into the tubing there should be no reason to expect a fault or failure. Since the test will only prove the system has no pressure leaks just using air to charge the zones is adequate, no need to fill the system with water now and then pressurize it to test it.
Once it confirms the pressure test, we'll blow it clear and then fill it with 50/50 water glycol or whatever is recommended for in floor heating systems. He'll likely get the electric boiler from Menards.
Here is the most recent pic of his build as of today:

Two car wide on the right and 24' deep. Tall one stall on the left for his Isizu 1.5 ton dually truck, which is 11' tall. Floor to peak inside on the left is close to 18' inside. The right side will have a mezzanine above the two car storage lifts. So he'll have to insulate it well to make sure the two heat zones in the floor can keep up with all that vertical space to heat. In that respect, he may be best off to create an interior second floor unheated storage space instead of heating all that vertical space.