spongerich
Well-known member
Every Thing You Always Wanted to Know About Electrolytic Rust Removal* But Were Afraid to Ask
Since it seems to come up very frequently, I thought I'd take a shot at writing a FAQ / How-To guide for using electrolysis to remove rust. Comments, corrections, additions are of course more than welcome.
What is Electrolytic Rust Removal?
Electrolytic Rust Removal (AKA Electrolysis) is a process that uses a low voltage DC current to remove rust from any ferrous metal item. The process affects only the rust and does no harm to any un-rusted underlying metals. It's one of the safest and gentlest processes for rust removal, which is why it is about the only method used by museums for preservation and restoration of iron and steel artifacts.
Can I do this in the comfort of my own shop/garage?
Absolutely! Electrolysis is simple to setup and quite safe as long as you follow a few common sense guidelines. A complete electrolysis setup can be made for $25-30, but you probably already have almost everything you need in your garage, shop and basement.
Am I going to blow myself up, get electrocuted, get poisoned, ruin my great great grandfather's vise?
No, no, no, and definitely no.
There are a few things to keep in mind before you get started. You will be using a battery charger or other low voltage DC power supply that plugs into 110V AC house current. You'll also have a big bucket or tank of water nearby, so use your head and make sure that you locate your charger someplace that it's not going to fall into your tank. Also take care to keep cords and plugs in a safe place. Use a GFCI protected outlet. Wear rubber gloves, wear eye protection, wear a condom. The 12V DC side of things is safe enough.. I've forgotten to unplug mine and reached into the tank to move an anode a couple of times, but it's best to unplug things whenever you're working on things.
The electrolyte itself is simply water and some Sodium Carbonate. (More on that later). Sodium Carbonate is safe, though you should wear gloves and avoid breathing it or getting it on your skin or in your eyes. If you do, just flush with plenty of water and you'll probably live. (If you don't, can I have your stuff?)
As for grandpa's old tools, electrolysis will not harm them. As long as you always hook up the negative side of your circuit to your tool, it will be unharmed. Only iron oxide is removed and neither the electric current nor the sodium carbonate solution will affect the good metal underneath, even if you leave it in there for a month. Care should be taken with non-ferrous metals and other non-metalic parts to avoid having them in the solution. Wood is usually ruined. The sodium carbonate solution turns most wood black, so handles etc should be removed if possible.
If your part is painted or plated, paint or plating that's intact and securely attached won't be harmed. Loose paint will usually come off in big sheets. Cast iron pieces like machinery parts usually end up stripped of their paint.
OK, I'm ready to do this. How to I start?
You'll need to gather a few things before you begin.
- A low voltage DC power supply. A battery charger works great for this and since you're here at GJ, you probably already own one. Older or cheap ones sometimes work better than newer fancier units since some of them have intelligent charging functions and they won't provide current if they think your “battery” isn't charging. If you find that you're putting out close to 0 amps, you might have this problem. If that's the case, just pickup a crummy old battery charger from a yard sale for $3.00 or get yourself an old power supply from an unwanted computer. (You can do a Google search on “Converting an ATX power supply to a bench power supply for all the gory details of what to do.. takes about 5 minutes) You can use any DC power supply that you have handy. I don't recommend anything more than 24v DC for safety. Also, too much current will waste energy heating up your electrolyte and you can potentially boil it if you use a large power supply with a small tank.
- Sodium Carbonate. The easiest place to get this is to buy a box of Arm and Hammer Super Washing Soda. You can find this with the laundry detergents/additives in most grocery stores. It's cheap, and a box will last you quite a while. Washing Soda is NOT the same as Baking Soda. Baking Soda is sodium bicarbonate. Baking soda doesn't work well as an electrolyte. If you can't find Washing Soda, you can convert baking soda to sodium carbonate by cooking it in your oven at 300 degrees for about an hour. It's suggested that you wait until your wife goes out before you do this.
- Sacrificial Anodes. (What the heck are those?) Sacrificial anodes can be just about any piece of iron or steel that you don't mind seeing ruined and/or consumed. An ideal anode is the same general shape as the item that you're de-rusting. Museum curators often use expanded steel mesh and form fit it around the artifacts that they're preserving. That's not really necessary for that old ratchet you found in the junk yard. A couple pieces of re-bar or an old crankshaft works just fine. In my opinion, the best sacrificial anodes are pieces of carbon graphite rod or plates. The biggest advantage of using graphite is that the whole tank stays much cleaner. They also last a very long time. When you use iron/steel, it accumulates rust and leaves a thick layer of orange sludge floating around your tank. You'll need to stop periodically to clean the rust accumulation from the anodes to keep everything working efficiently. Graphite anodes seem to shed whatever iron oxide they attract and it doesn't sludge or foam up in your tank. You can find graphite rods at welding or glass blowing supply places or on the Intertubes, eBay, Amazon etc. If you're just doing a couple of things or want to start RIGHT NOW, go ahead and look in the corners of your garage for some metal.
IMPORTANT HEALTH SAFETY NOTE: You should never, never, never ever use stainless steel for your anodes. Stainless steel contains chromium and it will cause hexavalent chromium (chromium VI) to precipitate out into your electrolyte. Hexavalent chromium is a nasty carcinogen and is responsible for several Superfund cleanup sites. Take a look at http://www.hexavalentchromiumdangers.com/ to see for yourself how bad this stuff is.
- A plastic bucket, tank or other non-metallic container. You can use just about anything that's large enough to contain your item (plus a little room for your anodes). Anything from a 1 gallon plastic bucket up to a wading pool or a big hole in the ground with a plastic liner will work. Some people have used metal containers and just used the container as the anode, but that gets messy and it will eventually be eaten down and get holes in it. You also have to take care to avoid letting your tool etc touch the sides. I like using a 5 gallon Spackle bucket for smaller stuff and a larger RubberMaid tub for larger things.
- Some wire to hook everything up.
.... continued in next post.....
Since it seems to come up very frequently, I thought I'd take a shot at writing a FAQ / How-To guide for using electrolysis to remove rust. Comments, corrections, additions are of course more than welcome.
What is Electrolytic Rust Removal?
Electrolytic Rust Removal (AKA Electrolysis) is a process that uses a low voltage DC current to remove rust from any ferrous metal item. The process affects only the rust and does no harm to any un-rusted underlying metals. It's one of the safest and gentlest processes for rust removal, which is why it is about the only method used by museums for preservation and restoration of iron and steel artifacts.
Can I do this in the comfort of my own shop/garage?
Absolutely! Electrolysis is simple to setup and quite safe as long as you follow a few common sense guidelines. A complete electrolysis setup can be made for $25-30, but you probably already have almost everything you need in your garage, shop and basement.
Am I going to blow myself up, get electrocuted, get poisoned, ruin my great great grandfather's vise?
No, no, no, and definitely no.
There are a few things to keep in mind before you get started. You will be using a battery charger or other low voltage DC power supply that plugs into 110V AC house current. You'll also have a big bucket or tank of water nearby, so use your head and make sure that you locate your charger someplace that it's not going to fall into your tank. Also take care to keep cords and plugs in a safe place. Use a GFCI protected outlet. Wear rubber gloves, wear eye protection, wear a condom. The 12V DC side of things is safe enough.. I've forgotten to unplug mine and reached into the tank to move an anode a couple of times, but it's best to unplug things whenever you're working on things.
The electrolyte itself is simply water and some Sodium Carbonate. (More on that later). Sodium Carbonate is safe, though you should wear gloves and avoid breathing it or getting it on your skin or in your eyes. If you do, just flush with plenty of water and you'll probably live. (If you don't, can I have your stuff?)
As for grandpa's old tools, electrolysis will not harm them. As long as you always hook up the negative side of your circuit to your tool, it will be unharmed. Only iron oxide is removed and neither the electric current nor the sodium carbonate solution will affect the good metal underneath, even if you leave it in there for a month. Care should be taken with non-ferrous metals and other non-metalic parts to avoid having them in the solution. Wood is usually ruined. The sodium carbonate solution turns most wood black, so handles etc should be removed if possible.
If your part is painted or plated, paint or plating that's intact and securely attached won't be harmed. Loose paint will usually come off in big sheets. Cast iron pieces like machinery parts usually end up stripped of their paint.
OK, I'm ready to do this. How to I start?
You'll need to gather a few things before you begin.
- A low voltage DC power supply. A battery charger works great for this and since you're here at GJ, you probably already own one. Older or cheap ones sometimes work better than newer fancier units since some of them have intelligent charging functions and they won't provide current if they think your “battery” isn't charging. If you find that you're putting out close to 0 amps, you might have this problem. If that's the case, just pickup a crummy old battery charger from a yard sale for $3.00 or get yourself an old power supply from an unwanted computer. (You can do a Google search on “Converting an ATX power supply to a bench power supply for all the gory details of what to do.. takes about 5 minutes) You can use any DC power supply that you have handy. I don't recommend anything more than 24v DC for safety. Also, too much current will waste energy heating up your electrolyte and you can potentially boil it if you use a large power supply with a small tank.
- Sodium Carbonate. The easiest place to get this is to buy a box of Arm and Hammer Super Washing Soda. You can find this with the laundry detergents/additives in most grocery stores. It's cheap, and a box will last you quite a while. Washing Soda is NOT the same as Baking Soda. Baking Soda is sodium bicarbonate. Baking soda doesn't work well as an electrolyte. If you can't find Washing Soda, you can convert baking soda to sodium carbonate by cooking it in your oven at 300 degrees for about an hour. It's suggested that you wait until your wife goes out before you do this.
- Sacrificial Anodes. (What the heck are those?) Sacrificial anodes can be just about any piece of iron or steel that you don't mind seeing ruined and/or consumed. An ideal anode is the same general shape as the item that you're de-rusting. Museum curators often use expanded steel mesh and form fit it around the artifacts that they're preserving. That's not really necessary for that old ratchet you found in the junk yard. A couple pieces of re-bar or an old crankshaft works just fine. In my opinion, the best sacrificial anodes are pieces of carbon graphite rod or plates. The biggest advantage of using graphite is that the whole tank stays much cleaner. They also last a very long time. When you use iron/steel, it accumulates rust and leaves a thick layer of orange sludge floating around your tank. You'll need to stop periodically to clean the rust accumulation from the anodes to keep everything working efficiently. Graphite anodes seem to shed whatever iron oxide they attract and it doesn't sludge or foam up in your tank. You can find graphite rods at welding or glass blowing supply places or on the Intertubes, eBay, Amazon etc. If you're just doing a couple of things or want to start RIGHT NOW, go ahead and look in the corners of your garage for some metal.
IMPORTANT HEALTH SAFETY NOTE: You should never, never, never ever use stainless steel for your anodes. Stainless steel contains chromium and it will cause hexavalent chromium (chromium VI) to precipitate out into your electrolyte. Hexavalent chromium is a nasty carcinogen and is responsible for several Superfund cleanup sites. Take a look at http://www.hexavalentchromiumdangers.com/ to see for yourself how bad this stuff is.
- A plastic bucket, tank or other non-metallic container. You can use just about anything that's large enough to contain your item (plus a little room for your anodes). Anything from a 1 gallon plastic bucket up to a wading pool or a big hole in the ground with a plastic liner will work. Some people have used metal containers and just used the container as the anode, but that gets messy and it will eventually be eaten down and get holes in it. You also have to take care to avoid letting your tool etc touch the sides. I like using a 5 gallon Spackle bucket for smaller stuff and a larger RubberMaid tub for larger things.
- Some wire to hook everything up.
.... continued in next post.....
Last edited:


on This^^^