By pex alternative I'm assuming you mean "csst"?
No . . . CSST is Corrugated Stainless Steel Tubing . . . some people call it TracPipe as that is one of the manufacturers.
IMHO the risk of using csst is too great due to lightning strikes, and burned down houses that have occurred prove it. Here is csst propaganda website that acknowledges lighting risk and explains electrical bonding & grounding that is critical for csst.
http://www.csstsafety.com/CSST-FAQs.html
For
ABOVE ground natural gas piping, IMHO best material is
black pipe steel. It's cheap at around $1 foot and extremely safe.
For NG piping between buildings (ie
buried under ground), the best choice is
yellow plastic polyethylene pipe (thick wall IPS - - iron pipe size). You direct bury the plastic yellow pipe and use risers at each end that transition the plastic to steel above ground. Risers are either fused with the yellow plastic pipe, or a Stablock connector is used (ie much like "Push To Fit" for water - - aka SharkBite). Tracer wire is wrapped around the buried yellow plastic NG pipe so it can be located later.
Now the "PEX stuff" that was mentioned refers to very new technology of NG style plastic pex that have crimp connectors at each joint. There was recent This Old House TV episode where it was used to connect NG supply from outdoor meter around perimeter of house to customer's BBQ grill. It takes special crimper machine (ie squeezing jaws) that permanently connects each joint. I'd skip this for now as it's brand new technology.
FYI - - - to easily find prior GJ threads on NG pipe use Google & search:
. . . . buried natural gas pipe site:garagejournal.com
https://www.google.com/?gws_rd=ssl#q=buried+natural+gas+pipe+site:garagejournal.com