I have looked for and have not found any authoritative evidence indicting the use of electrolysis to derust chrome plated objects produces chromium 6.
If you have such knowledge or evidence I would greatly appreciate knowing.
This has been an ongoing debate for a long time. Here is an archived thread that goes into it a bit from this site:
http://www.garagejournal.com/forum/archive/index.php/t-157953.html
I have not ever found any "authoritative evidence" proving either it does or it doesn't, honestly.
There are several things that do concern me a bit:
1. Hex chrome is produced from welding, cutting, melting, or other "hot work" of chromium containing metals.
2. Hex chrome is produced in commercial electrolysis & plating processes (again to be fair, usually high temp and very high current).
3. Chrome plating already has minute amounts of hex chrome.
I do not find the test kits to be viable for our use. The hex chrome test kits are based on the reduction of hex chrome to chromium (III) using diphenylcarbazide as an indicator. Like many test solutions that rely on colorimetry the red/purple colors can be difficult to differentiate. False positives/negatives are not unheard of for testing hex chrome due to it's reactivity with iron and lots of other things. Additionally, the test kit needs a clear solution, and my vat water is never clear after I run electrolysis.
Some of the automotive guys I knew used to talk about the dangers of chromium toxicity when using electrolysis for rust removal; they'd send bumpers and other chrome pieces off to the plating company to be stripped & re-plated rather than stripping it themselves.
For me, gambling with the potential risks is not worth it.
Sorry to thread-jack Blanco