4" thick new concrete?
That's a slab all by itself.
Right on top of the old slab, same exact footprint and all? And the old slab is 'stable' and in decent condition, except for the top being uneven?
Plastic sheet (thick vapor barrier stuff) to completely decouple the new concrete slab from the old slab underneath. Wrap the plastic past the old slab edges and down the corners/edges. Form the new slab with 2x lumber, right to the edges of the old slab, thus trapping the plastic sheet in place (think fitted bed sheet on a mattress). Pour new concrete slab on top of the old slab.
method = "unbonded concrete overlay"
http://www.cement.org/docs/default-...-07t-resurfacing-concrete-floors.pdf?sfvrsn=4
Note that local building codes may dictate different requirements, especially if there are seismic requirements involved.
Or break up existing slab, do proper sub-base prep, do form work, pour new slab as desired.
Your call. Check local code requirements first.