Good advice above.
OP, keep in mind that if you have a 100A service on the house, drawing 100A, or even 90A in the shop will likely result in tripping the main...BUT... Someday you or someone else may upgrade to a 200A on the house- so it would be nice to have a decent service wired.
If you run the 2" with the 2224 (capable of 90A) but put in a 60A breaker you will be in good shape now, and in the future.
Alternatively, still go with 2" PVC, but wire it with the wire you need for whatever smaller service you want now. Someone can always pull larger. The cost of 70ft of 2 inch conduit versus 1in conduit is a few lunches.
Oh, also toss in a piece of 3/4 for low voltage stuff you might need, Internet, alarm, whatever. I can't stand the sight of an open trench without spare conduits....
