In the New England heating season the rust will mostly be from condensation, not ambient humidity. Condensation happens when objects are cooler than the dew point of the air, so as long as your cast iron and raw steel near room temperature, your won't get condensation and rust, unless you're at 100% humidity. So it doesn't matter if you pick 36 or 45 or 50 or 60, just avoid huge swings in temperature and humidity. The problems happen when you have an uninsulated garage, or the doors are open, and you have a humid rapid warming from, say, 25 degrees F to 40 with rain. In northern Vermont I haven't had any condensation or rust issues since getting a insulated garage. I don't heat it but the insulation and airsealing temper the temperatures and humidity in the shop so I never have condensing conditions. I don't get condensation from warming it up from below freezing to 50-60 deg F in a few hours with the wood stove - probably because the winter air thats getting drawn in by the stove is very low humidity to begin with.