I've personally performed fit testing at work for hundreds of people. There's quantitative fit testing like corn chip described, and qualitative, which kd3pc described a simple version of. And as paulsomio mentioned, the smell test only works if the filter you're using will filter what you're using to "test". Most of what you'd encounter in a home shop would fall under exposures where qualitative fit testing is sufficient, even by OSHA standards.
The qualitative fit test procedure laid out in the OSHA standard has you go through a series of steps like breathing normally for a minute, deep breathing for a minute, reading out loud, moving your head around, etc., to simulate things you do while working that could break the seal. You do this while the person testing you maintains a concentration of a fit test solution (sweet stuff, bitter stuff, irritant smoke, etc.) that you'll be able to smell or taste if you don't have a good seal.
For home shop purposes, spraying something smelly but harmless that your respirator filters will remove, while moving around and talking, will get you "close enough" to a real fit test while not being OSHA approved. If you want to go the extra mile (and have a helper), the qualitative fit test kits are a couple hundred dollars and the procedure is laid out at
https://www.osha.gov/laws-regs/regulations/standardnumber/1910/1910.134AppA . There are instructional videos on youtube, and it's really not rocket science. Even doing it "professionally" requires no particular certifications or anything.
Or if you're not the DIY type (then why are you on this site?

), a lot of the places that do medical evaluations for respirator use also do fit testing...although I have no clue if they'll just fit test a random person if it's not for work.