You will all most never have a grounded conductor in a 3 phase plug. They make them but they are rather rare and have 5 prongs. So if you have a 3 phase receptacle that has 4 prongs you will not have a grounded conductor. You also may not have 220V/240V at the outlet, as that is not a given with 3 phase plugs either. In fact unless you have a 240v delta service you will not have 240V between the hot conductors. IF you do have a 240v delta service every third hot conductor will not be 120V to the grounded conductor. There is another low voltage common 3 phase system in use in the US called a 120/208 wye system. If that is what you have, you will not get more than the 208V between hot conductors (this can cause problems with some motors) but, you will be able to use all your breaker panel spaces for 120V use.
So
If you need a higher than 200V recepticle, either the delta or the wye service will be ok using any 2 hot conductors, and a grounding conductor.
If you need a 120V/240V ( 4 wire circuit ) You must make sure that you don't have the hot leg of a delta service as one of the conductors ( ie. about 200v to the grounded conductor) as your 2 hots in the circuit.
William...