Hi,
Saw this, which I was not aware of, or had heard about before.
We do want to stay safe!
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Compressed air mixed with non-CFC refrigerants and solvents can create flammable mixtures. The elevated partial pressure of oxygen increases the ability of all materials that can combust to become more flammable. It is the same as lighting a cigarette in an oxygen tent - what used to burn slow now can go boom.
Using nitrogen to leak check is much safer. AFAIK, no one has gotten themselves blown up using R-134a and air, but there have been fatalities from people mixing air and R-22 together at elevated pressures. The one that got the most attention was someone welding a tank containing R-22 and air - parts of the tank went over a mile, and there was no trace of the welders.
Both R-134a and R-22 don't burn at atmospheric presure in air, so are considered non-flammable. Materials that burn at atmospheric pressure in air are marked as flammable.