"it does release heat better than iron, nearly 4 times better dependent on the specific alloys involved. This is why many high performance radiators and air/water or water/water heat exchangers do use copper in when compactness is paramount, with or without fins."
You are referring to releasing heat to a liquid, as to radiating heat to air, as in the reference to an aftercooler you are incorrect. Rarely are heat exchanger air to air made from an alloy of copper deviating from a very high level of copper. Copper is a poor radiator unless it is oxidized to a very dark color (or painted to dark color); a chemically oxidized copper, basically oxidized to black is as good as black iron but no better, as any less than very dark oxidized copper it is a very poor radiator of heat. 4 times better, you would be correct if I was referring to heat conduction, copper conducts heat 5 times or more better than black pipe ( iron pipe which is actually low carbon steel)
https://www.spiraxsarco.com/learn-a...ng-principles-and-heat-transfer/heat-transfer
"emissivity has a lot to black body theory, and basically darker objects can absorb/emit IR heat faster than the same material that is shiny. This is irrespective of its conductivity and oxidized copper and iron has close to the same numbers."
Here you are confusing conductivity and the ability to radiate heat. Copper in any form bright or oxidized is great at conducting heat, with emissivity ( radiating ability) which copper is less then black pipe unless chemically treated or painted black. Copper does naturally oxidize with age but this level of oxidation still is not as good as black pipe.
"In fact one of the reasons that steam pipe is preferred to be iron pipe is it doesn't loose as much heat getting the steam from the boiler to the point of use compared to copper(there are several other reasons why iron is better in steam applications) "
In fact, you are getting your facts confused. Main reasons iron pipe was mainly used was
it was cheap, fuel was cheap, it is an excellent radiator of heat, steam pipes radiant loss feeding radiators not considered a loss due to internal use, copper was always expensive.
Lookup in the link below for the comparison of the radiant quality of copper vs steel/iron ...
iron oxidized (as in pipe), cast iron (as in cast iron radiator) and all forms of copper (note, copper pipe as in "oxidized" is copper pipe chemically darkened or oxidized over decades to be close to a very dark color)
https://docplayer.net/23945432-Infrared-thermometer-emissivity-tables.html