I was wondering why in the world someone would make a thread asking this.
Then I realized I would do something like that.
And then I also realized your the same guy who got his truck stuck on his brand new lift last week, suddenly the world made sense agian.
In my experience the decision of where the posts are on relation to the CG of the vehicle is not going to be up to you, but up to the lift arms themselves. Often times you dont have the adjustability of the arms in your favor and you have to get it the best you can, often times meaning more center of the car because the front arms just aren't short enough to make a good contact with the lift points.
Some trucks the arms just aren't long enough, on my 99 Silverado I have to lift the truck using underneath the leaf spring bushing as a lift point. Kind of sketchy but also the safest place, any optimal points along the frame is too far up the body and leaves the rear end tilted.
I once had to lift a vehicle where the lift point was designed to be use with the actual arm itself and not the adapter. I cannot for the life of me remember what it was and no amount of googling seems to jog my memory. I think either a bmw or Mercedes, I want to say it was a high end german vehicle, I remember being very put off and concerned about damaging the vehicles side skirt but it was actually more stable than most lift points on other vehicles.
Anyways point is, usually the lift is going to tell you where. Obviously you will be able to tell when you go to set the arms if you should and can move the car back for a more stable lift. I mean if the car is pulled way forward and you think to yourself "I can probably pull this car back a foot and lift it" then you should probably do so.
Another thing that is going to give you the best opportunity to get as close to CG as possible is making sure you pull the vehicle in between the posts evenly.
If you pull your car/truck and you have 1 inch between the left post and the left side of the vehicle, but you have 7 inches on the right, your going to have a difficult time getting to center gravity as the left side arm will be too long for its lift point and the right side will line right up.
In the end it's pretty much going to come down to what you have to work with and some common sense. I suspect you'll be fine