Joes169 has it about right. If someone is claiming 5000 psi concrete from a 5 sack mix, they are full of it. Compressive strength is a factor of water cement ratio, period. To get 5000 psi out of a typical 3000 psi mix design, you wouldn't be able to add enough water to get the concrete out of the chute. That's not going to happen in the real world.
To the OP's original question; If you haven't placed the slab yet, buy from a reputable company, keep the slump under 4" or use a mid range water reducer and cure the slab properly. Hire a testing lab to take a couple cylinders if you want to be certain.
If the slab is already in, hire a testing agency to do an in place test. It will cost a couple hundred bucks and your life - or at least your piece of mind - is worth more than that.