Most likely rust. I'd use a torch and heat around the bung. You need a torch large enough to heat the bung quickly enough that it expands before the heat soaks into the plugs allowing it to expand also. Large Crescent wrench with a cheater pipe.
thats what he means. get in there with high heat fast , before heat can transfer to the plug, then try to remove it . the fast heat expands the bung before it transfers to the plug giving it some relief