One of the reasons to use a condensing boiler is they frequently, but not always come properly and fully equipped with the outdoor reset controls and modulating burners to maximize efficiency. As well, they are usually sealed combustion and with the work that goes on in a garage and the **** we have in them, you definitely want sealed combustion. The condensate will typically have a Ph in the 3.2 range. Pretty hot on a concrete floor. If I was putting it below the slab I'd drill a large enough hole to get a well point thru and go a few feet down. If that water pools against the concrete it will over time consume it. You can use a neutralizer lit. Fill it with limestone chips and it will do its thing. Make your own with some 3"PVC a couple feet long, cap on one end and threads on the other. Get a couple barbed fittings on the end and connect it.
I once had a customer use a furnace I was representing as a construction heater. He set this condensing furnace on his new concrete floor, put a supply plenum on the top which he secured to the floor joists. He called me in the spring and I had to go visit the place. The furnace was hanging from the floor joists. The bottom 4" of the furnace were gone due to rust. This furnace had a 12ga base plate on it. His new basement floor had a 6' radius that dished out to about 2" thick. The exposed aggregate looked like it had been run thru a rock polisher.
Whatever you decide, why don't you measure the amount of condensate at different outside temps for your own info and report back on what you find. Whether oil, NG or LP, there is a potential per gal or therm of about 1.1 gal of condensate. You won't see that much, but it will be interesting to know how much there is.