Some you can, some you can't.
Takes less time to find out than to post asking about it.
With the drawers EMPTY (seen some stupid things in my time...) pull them out.
Look at the little levers on each slide. One thumbs up, the other down, the drawer pulls straight out.
After you get some drawers out of the way you will see the square holes that the slides go into. If you have 'extra' holes, you can move the drawers around.
The slides are easy to detach and reposition.
Now the bad news. After you get the drawers set the way you want, you may find they won't lock, or some won't lock.
On the lower priced boxes they put too few lock tabs on the locking bar(s).
So you may find that the lock tabs don't match up.
If this sounds confusing, it really isn't when you pull the drawers out and look at how the lock tabs on the bar(s) catch the back of the drawer.
Anyway, on a five drawer swapping them around takes just a few minutes.