Hi
This is what we refer to as a 'cove' and we carry Cove Mortar and curved Cove Trowels to make them. These are used and often required in commercial kitchens and labs and operating rooms. Also sometimes specified in public restrooms. The purpose of the coves is to allow for easy cleaning and no bacteria building in a hard-to-clean 90 degree angle vs a curve. Usually not ever needed for residential work unless you want it.
https://armorpoxy.com/products/cove-tool/
Cove Mortar is specially formulated to make coves and is an epoxy/aggregate blend. No liquid alone will do what you want.
You would apply duct tape about 4" above the floor for a clean edge, then mix up the mortar and apply to floor edge/wall, make the cove with the Cove Tool, remove the tape, let that cure, and then do the floor onto the lower part of the cove. It's not easy work for a novice and does require a bit of technique and training to get them 'right'.