Thanks for the replies. I cut a piece of pvc on the chop saw once and it shattered all over the place so I was just wondering if there is a better way. I have to cut 56 of them.
This usually happens because the stock is not firmly supported while cutting!
To get the best and safest cut possible build a wood sled/fence for your miter saw. It doesn't need to be fancy, just make a strong back with 2x6 bottom and 2x4 back about 2 1/2 times the length of the picket. Keep the fasteners out of the center where you will be cutting! Solidly attach it, centered, to the bed of the saw however you see fit. I drill holes thru all of my saw fences so I can screw fixtures of all sorts from behind.
If you can adjust the depth of cut on your saw, adjust it so you don't cut thru the 2x6. If it's not adjustable you can tape a small block of wood to the blade depth stop, or stop pushing down once the part is cut. If you use the stop cutting method try to keep the electric brake from cutting thru the bottom.
Now you have a zero clearance fence/table which will greatly reduce tearout and fully support your stock. It is long enough to clamp a stop on each end to keep any picket details centered if you need to cut both ends.