Boy, there's a whole whack of information required to answer each point of your questions, but I'll give you my condensed version. Welcome to the forum BTW.
No, various electric heaters don't heat better or worse than any other, it all depends on the application. Get the right type of heater, the right number, in the right size, placed correctly in your shop and you'll be happy.
1. Is this a personal/hobby shop, or work related? Farm?
2. What type of work/play are you planning on doing there?
3. What temp are you planning on keeping it during the winter?
4. How often will you be opening man-doors or garage doors?
5. What's your budget?
6. Heating all winter, or just when you're out there?
"Best" heating system: in floor radiant heat. If you open and close garage doors a lot, you can even add fan forced unit heaters in addition for quick warm up. But this costs the most.
Ceiling mounted electric radiant panels or wall mounted cove heaters would be second best. Radiant heat is always the most comfortable, no drafts, and completed quiet, but you need more of them in electric to have even heat.
Fan forced unit heaters are the cheapest to install, but obviously noisier, and less comfortable as your skin always feels moving air as colder than still air. Plus, 14' ceilings mean lots of heat stratification unless you keep your ceiling fan going all the time, but there goes the moving air issue again.
How many KW needed in total? You need a proper heat loss calculation, then everything is clear, not jus WAG. From personal experience, I heated my previous home's attached garage with 9 watts/sq. ft and it worked well (R12 walls, R40 ceiling, insulated garage door, Canadian prairies), but it did take a while to heat to 50F from cold as I only heated intermittently. Less important if you oversize electric heat than fuel burning heaters though.
Check out these:
http://www.appliedradiant.com/elect.htm
look at the Alcatel electric heating cable.
http://www.ouellet.com/commercial-heating-system.aspx
This will show a bewildering array of heater types.
This should be a good start on your journey.
