Just a little explanation, as I have seen similar questions before. On a 120 volt circuit, the current goes out on one hot wire and returns on the neutral. On a 240 volt circuit, the current goes out on one hot wire and returns on the other hot wire; the neutral doesn't carry any current in this case. (This is assuming no 120v load on this circuit.) This is the reason for the two breakers; each one can carry 100 amps. More commonly used is a double breaker, which has two legs, but serves the same purpose.
HTH, Brady