I've already done the bondo trick on it a few years ago. Now the whole corner is gone
That's the trouble with bondo. Rot is a fungal infection. Remove the soft part left behind, and there's still plenty of fungus just ahead of it. Adding bondo to the hole just seals it in.
When it comes to something as thick (and as replaceable) as a sill, total replacement is the way to go. PVC is a good idea, but I'd worry more about proper flashing and keeping the water draining as it should.
When I bought my house, I had a big problem with the mullions in a couple of original windows from 1929. These were still largely there, just starting to go. I was able to save the wood using CPES, and then replace all the putty (how the water got in in the first place. The CPES has solvents that go past the rot and kill the fungus. It's water thin. Way too thin to build up missing wood, but thin enough to soak through soft parts and rescue them. Once treated, you can always bondo on top of this.
A couple of other windows were just too far gone to be saved. I've got nice Pella replacements there now.