If you want fresh air in your shop with some heat recovery, sure this would work. You’d just want to build a filter for the stale air return using standard 16x25x5 filters for best results. Uses PSC motors, so likely around 180 watts on the highest speed. That unit is around 60% efficient, so not outstanding…but if it’s free…
159 CFM is the max flow, so you can figure out air exchanges given the volume of your shop. Remember this is an HRV so in hot humid conditions would introduce a lot of moisture..you’d want an ERV likely if using AC in a hot/humid climate.
How big is your shop? You’d need two external vents, 6”, at least 10’ apart. If you just want a scrubber with no outside air, it makes zero sensor to use an HRV for this.