Wall anchors need to be 1/2" hot dipped galvanized bolts, no more than 12" from the corners with spacing no more than 6'. That's per IBC 2006 which is pretty normal. If you do not have anchors, it would be a good idea to drill for some and epoxy them in. I'd use anchors like you might use for a lift. Cement screws - no, not even. Also - your bottom late needs to be treated lumber, so use only hot dipped fasteners in that ot they will dissolve. No regular nails.
If I was doing it, I would start by marking all your top and bottom plates all the way around. If doing it solo, break each wall into two sections. The long walls should run complete, so make corners for those and build one 15' section on the slab. For the end walls, build twp 12' sections, measured from the back. Stand up one 12' and one 15', brace and plumb the corner, brace and plub the ends and put a diagonal on top to hold them up. Then build the next 11' 5"' end section and stand it up, then maybe another 15' section in the front. Repeat for the other end.
You should also lay out your doors, windows, etc in the walls while they are on the ground.
See Post #37 here:
http://garagejournal.com/forum/showthread.php?t=100482&page=2