I had convert my mode from propane to natural gas, so I have went through this exercise. My was a 75K BTU unit and had the labeling on the side, so it was pretty straight forward.
A 45 orifice is a .082 dia hole. For LP at 11" W.C. pressure, that works out to 46969 BTU output.
If the new valve was setup as NG specific, then the pressure range is set much lower than propane but it is not set to a specific number as different appliances run at different pressures.
1) You need to get a manometer and adjust it to 3.5" W.C. (That's what my unit labeling said for example). You can make your own manometer, goggle it but your on your own. I had a local connection, so he dialed it in for me.
2) Obtain the orifice size that has the same BTU output as the LP fuel at 11" W.C. In this case, if you run NG at 3.5" W.C. pressure, you need a number 29 size orifice and that gives 46961 BTU output.