Would be helpful to know more about the smoke detectors. When you say hard wired with battery back up I assume you mean they are 120 VAC with an internal battery back up in each detector. Is there a third wire used, typically red, that allows the units to communicate with each other. Hardwire with battery back up can also mean a low voltage system, like 12 or 24 VDC with a central battery back up, which is what I had at a previous home all integrated with the security system.
Newer smarter units, such as the NEST Protect do a monthly test to ensure the sounders in each unit are working. They have a built in microphone to listen to make sure there is an audible alarm. That occurs typically once a month, at predetermined times. They also have a confirmation light that lets you know all detectors are communicating. If any detector is approaching End of Life you will get a different confirmation.
Lastly, are any of the units also CO detectors and perhaps they are picking up something there.