Re: How does a propane refridgerator work
Gas, or propane, refrigeration had a small but important market share through about the late 1930's, primarily for rural and remote applications. In 1935 the Rural Electrification Act was passed, and both wind-powered and alternative energy devices were quick to disappear from the scene. Removal of competing technologies was a requirement for the new and convenient electrical service hookup.
I can't recall the exact history, but (I believe) that Arkla and Servel combined in the 1950's, marketing both residential cooling and refrigerators, and continued up until the late '70's(?).
In my prior home I had a Servel forced air AC unit, in conjunction with HW baseboard, for one of the HVAC arrangements I tested. Because the AC unit was located outdoors, the unit suffered from the elements (rust), and eventually became too much of a nuisance. Maintenance was relatively straight forward, but far more frequent that the typical condensing unit, and I spent a lot of time just looking at the innards trying to figure out what had gone wrong. As the cost of natural gas rose in my area, the case could no longer be made for the device and it was replaced with a conventional unit.
The theory behind the unit is as Hoosier Buddy describes, using ammonia as the medium. As the use of chlorofluorocarbons is reduced or phased out, these systems are getting renewed attention - especially for larger applications. In fact, they are still in use today for many large meat, ice cream or frozen food processors. Ammonia is indeed the refrigerant of choice for many pharmaceutical or industrial users.
Ammonia is referred to as refrigerant R-717 and should be handled with some care:
http://www.osha.gov/SLTC/ammoniarefrigeration/index.html
Here is a nice schematic illustrating the refrigeration process. It is the same compression/expansion as a standard condensing unit:
http://www.nhtres.com/differs.php
I fear that these devices are becoming very scarce, as is the knowledge to maintain them - precisely as much of the knowledge of steam systems have been lost over the last century.