Sometimes you just gotta be destructive.
For example, some HHRs (inexplicably popular around here, and they EAT rearward front control arm bushings) the bushing will be so worn that the bolt, when siezed to the metal sleeve at the center of the bushing is turned, the entire bolt/sleeve spins the the rubber. In cases like this, I cut the rubber down with a torch, then heat the metal sleeve to a lovely orange and grip it securely with vise grips and them apply an impact wrench to bolt. Works pretty much without fail. Sometimes if I'm replacing the control arm in its entirety, I will use the recip saw to cut the arm off the car and make life a little easier.
One method that works well is to back the nut or bolt off as much as possible, spray liberally with a p-oil, and then over tighten the fastener.
If the sleeve in the middle of your bushing is still well attached to the surrounding rubber, apply a LOT of heat to the head of the bolt (get a nice orange, almost white) and then let it cool for two to three minutes (stay vigilant and be ready to put out the bushing if it ignites). Then rip her out with an impact.
If you are working off the car, easy mode is on. Apply enough force in one direction and you WILL win. Heat and p-oil are force multipliers.