If you use good quality components (ie. stainless steel manifolds, etc.) and fill the system with a 50/50 mix water/propylene glycol, I don't see why there would be any corrosion issues. You might want to have a thermal break between the two slabs to prevent heat conduction from the slab you are heating to the unheated one. I used a vertical piece of high density foan in my system for this (insulated door cutouts).