Lots of really good info here. I believe the holy grail right now is still 2-3" of spray foam with mineral wool inside that. So would be exterior siding, moisture barrier (tyvek, zip, etc.), sheathing, 2-3" of foam (look, there are charts for your climate zone) then mineral wool/rock wool/roxul, etc. and finally drywall. The combo of drywall primer and latex paint on the inside is the barrier. Nothing else needed.
When I did my garage I did the walls first. It did very little (heat rises). I didn't do any foam, just mostly blown-in and some of whatever I had laying around (roxul, pink r-13, etc.). Just walls only being insulated was a little noticeable but honestly very little. Ceiling/roof was where the big gains were.
This is a great link for the underside of a roof deck:
https://www.greenbuildingadvisor.com/article/how-to-build-an-insulated-cathedral-ceiling
I'm new, if it won't let me post links then just Google:
"green building advisor insulating a cathedral ceiling" (from November 8, 2011) It'll come right up.