On a sunny day, especially with a dark-colored roof, you could easily have temperatures in the attic considerably higher than ambient - 30 to 40 degrees are not unheard of. While you could possibly work with this, I would not recommend such an installation.
As a general rule, I have always specified the location for OA sensor as a north wall or eave where there would be no impact from sunlight. Location should be representative (i.e., not next to the clothes dryer outlet, etc.).
Equally important is to scale the correct operation of the sensor. For example, using Anchorage (no climatic data is available for Palmer), a 99% design temperature is -9 degrees F. A reset schedule might read as follows:
Boiler shall fire to maintain (circulating loop? Modify to suit.) HW temperatures as described below:
At outside temperatures above 60 degrees F , as noted by OA sensor, system shall remain in enabled status. HW Pump shall de-energize and boiler burner shall not fire.
Upon drop in OA temperature below 60 degrees F, the HW Pump shall energize. Upon confirmation of flow (flow switch), Boiler shall fire to maintain HW (circ. loop) temperature of 140 degrees F as determined by (circ. loop) aquastat. Under no circumstance shall minimum operating temperatures exceed the safe limits of the boiler as determined by the boiler manufacturer.
Boiler firing shall modulate in a linear fashion such that the (circ. loop) HW temperature shall maintain 180 degrees F at 10 degrees F OA temperature.
All operating setpoints shall be user adjustable. Boiler operation shall be disabled unless flow is confirmed.
Something like this, modified to suit your particular needs, is recommended as a starting point. Be aware that any system will require a commissioning period and some "tweaking" for optimal operation. You are starting to get into the more complicated realm of temperature controls and they are generally not "optimised" right out of the box.
Be aware also that the the various control devices must communicate with each other so that a common operating voltage is very useful.
Getting even fancier, you could also include flue gas temperatures, time of day, etc. into your sequence of operation, as well as fuel usage for your operating cost summaries. Once you have a computer into the system, you can tweak to your heart's content.
Good luck with your project.
as always, offered only as opinion