In a woodworking shop I'd recommend scissor or parallel chord trusses for the extra clearance. Sheet goods or any long board becomes easier to move.
Or are you going to have tall sidewalls to start with?
Also, you'll have more inexpensive options to add a lot of R value over the 2x4 R-19 batt insulation you're considering with your standard trusses.
I'm pretty sure that you'll end up with a well insulated roof for a similar or cheaper price as regular trusses plus spray foam.
Another option if you stick with regular trusses is to put rigid foam with an air gap between the top chords. Some people skip the air gap and push the foam all the way up to their sheathing, thereby making it an unventilated roof. Not sure if that's acceptable in your area.
You mentioned Menards. On their website they carry a roof decking foam called Valutherm that seems priced well compared to expanded polystyrene.
Here is a link to the 3" product which would allow you to install between your upper chords with a 1/2" gap.
http://www.menards.com/main/buildin...decking-insulation-board/p-1485634-c-5779.htm
As far as drywall, again I think you'd like a painted surface for reflecting light in a wood shop. And it's great fire protection.