I have seen a red iron frame metal building with a concrete block stem wall. The frame was put up on the slab, as usual. Then, before the wall sheet metal was put up, the blocks were laid between the framing members. Two rows of 8" blocks and a cap block to cover the holes. After the walls were covered, the blocks were exposed inside and outside, and were not structural.
Lots of commercial red iron framed buildings have masonry fronts to dress them up.
It is the same principle as what you want to do, just on a larger scale. The bottom line is you will have to work with your building supplier or contractor, tell them what you want, and they will tell you what they can, or can't, do. If one can't do what you want, someone can. Keep looking.
jp