UHMW is pretty slippery stuff. And under pressure it can crack. I really don't see it as a good vise jaw material.
When I bought my Wilton 4", I moved the Littco 3 1/2" to a different bench, and made aluminum jaws for it. That's come in pretty handy actually.
I've got a copper thingie that I often use for grabbing threaded parts, and some pieces of lead sheet for the more sensitive metal things.
Whenever that's no good, I've got the wood vise. 3/4" maple jaws. That's no more damaging than UHMW, but should last at least as long, and isn't slippery.
I've put a linseed oil finish on them, which is reasonably resistant to glue, etc.
I also have a panavise with rubber jaw covers.
I guess you could glue a rubber mat to wood jaws for things that wood isn't ideal for, but I can't really see other plastics being good for vise jaws.