"Collectible", yes - although that's a pretty narrow market niche.
That set I posted above has been up
on ebay for well over a year now.
"Unique" - to a degree, yes. They were one of very few makers of 1/4" hex drive sets, and one of the only ones to mark the sockets "U.S.A."
(Meteor stamped "U.S.A." on them, but they didn't make a hex drive set.)
That odd socket is described as a "radio" socket in some early catalog advertisements. As noted, used for the round, knurled nuts found in early radio equipment.