If you could get us a closer shot of how the panels end at the slab, that will tell us a lot more. My buildings panels end with a angle trim under the bottom and it runs up about 2" behind the panel, all of this on the outside edge of the slab, and lower than the top of concrete.
If your is flush, I'd recommend using something like Silka flex, may be able to get in color. This is a single part polyurethane that is just plain tuff. I would put on the outside as I'd be concerned if caulked on the inside, water under the steel sill may cause it to rust.
Sometimes you may need to caulk the trim around the roll up.
Hope this helps