Looks like the front beam is a W beam and the back 4 are I beams to me.
I think you're right. Comparing the beams with dividers on the screen, it looks like the front beam is a 5x8" as stated (I'd call it an H beam) and the other four are 4x8". The flange shape is different- so the amount of material in the flanges is probably about the same. I'm not enough of an engineer to say how this effects strength - more homework is needed!
You might also bring a scale- the weight of a beam per unit length is also a spec; weigh one end and double. The supports aren't quite at the ends, but close enough for a first approximation.
My first thought was galvanized steel too, but the color of weathered aluminum and weathered galvanized is so similar it's impossible to tell from a picture that's been filtered through who knows how many computers and monitors.
(also, some people can't tell the difference or don't accept that there is a difference. One post here a member talked about aluminum framing studs and got downright huffy when I questioned that, having never seen any metal studs but galvanized and plain steel)
I'd suggest getting load charts from several manufacturers based on your best guess of size and material, take the charts (along with a magnet!!) and go see the stuff in person. Be prepared with a trailer and suitable supply of Benjamins - no deal beats cash and carry.