Looking at the spec sheet for the Schneider HEPD series, my takeaway is that they increase the warranty period and "insurance" coverage as you step up from the 25 to the 50 to the 80. But that doesn't mean it's going to stop an individual surge better. Think of it like the difference between a 6, 9 and 12 year water heater, which is usually a combination of better anode(s) provided and bigger numbers printed on the paper. They all get your water to the same temperature.
In this case, the 80 may be packing more MOVs (the active components used in SPDs) and fuses into the box, but it's not really clear. And all it takes is ONE MOV to stop a surge. The reason for having more than one is that MOVs are consumables. Every surge event erodes them a little, and having a 10 in parallel means you'll get 10 times the life out of them. That may matter in a really poor power environment (commercial), but probably doesn't matter in most residential cases (especially on 200A and smaller feeds). Alternatively, you could just install two of these. By Schneider's logic, two 50's in parallel would equal 100.
There IS however one huge difference between the external Leviton and the Schneider SPDs that I spotted when I looked closer. The Leviton has no N-G protection (notice, no green wire). That's fine, IF you're installing this in a main panel at the neutral-ground bond point, but you want an SPD with a green wire if you're installing in a subpanel.