Wear your safety glasses! I know way too many guys who refuse to wear them and have done permanent damage to their eyesight.
screwdrivers are not multitools! I have seen shafts explode when being used as a chisel and I have busted my knuckles more than once using one as a prybar and having the shaft or handle give out.
Gloves are a necessity, though they may be bulky and hard to work with, wear them when you can a pair of leather work gloves saved my dad's finger from a dump truck tailgate.
Don't lift heavy items alone, use a hoist or another guy to prevent back damage, trust me.
Keep a clean workspace, you don't want to be slipping on oil or tripping over hoses left on the floor
Use a torque wrench, it's easy to over torque a bolt and cause damage especially on aluminum parts
If your not sure just ask, somebody in the shop is bound to know
Make sure to depressurize a hydraulic system before draining the tank, you only learn that the hard way once
Let an engine cool down before draining the oil, it gets hot and will leave a nasty burn on you
Sorry for the lengthy response but I too am a beginner and have learned a lot of things the hard way as well as witnessed things go wrong for others and the results can be life changing