Both require using stainless or bronze pumps (or perhaps even monel if the water is corrosive such as lake sourced). Oxygen barrier allows you to use steel pipes, etc. Now if you're using a glycol filled system that has corrosion inhibitors, I suppose the barrier isn't necessary, but it still won't hurt, and it doesn't cost much anyway.
Wood boilers don't have stainless pumps, most are steel as well (some are stainless).
This oxygen thing is something perpetuated by old wives tales through the years.
Should be flushing the water every few years anyhow.
How many house water pipes are steel? They last what, 50, 60, 100 years? The oxygen isn't eating those up in months.
Just the same as the utter bull all over the internet about needing "special" glycol in heating systems. Have to use our "special" blend that's $40 a gallon.
A automotive coolant system is pretty much a boiler and heat exchanger. It runs much hotter, tons more heat cycles, more mixes of alloys and materials.
Failure can cost 20,30k+ on big engines.
Aside that EG is poisonous if you decide to drink it, there's no reason it won't work fine.