What is wacky about the chart? There are multiple different pumps used in that chart, from tiny (2cfm) to absolutely huge (almost 100cfm). Not sure what the 'W' stands for in the model number, but the second letter is 'S' for simplex and 'D' for duplex. The third letter is for the pump. So looking at that letter, you can see which models use that same size pump, with different specs based upon different pump speeds and motor sizes.
What is confusing you on the pulley size? It doesn't need to be in the chart. You select the motor and pump pulleys to achieve the proper pump RPM, for whatever speed of motor that you are using. So long as you are within the allowable RPM range of the pump, you can use any size motor that will produce the necessary horsepower to run the pump at that speed. Using a bigger motor than necessary will work just fine, and the motor will run cooler.
If the unit you purchased has two 1/2HP motors on it, I've got bad news for you: you have the smallest pump. With both pumps running, you're going to be getting 4.2cfm @ 80psi. That will air up some tires, run any type of air nailer, and a blow gun. Running off of the tank, you'll be able to run air tools for short bursts. No continuous-use air tools.
HTH!