Great topic!
I keep mine located more point of use; I also keep a stock of PPE items in a cabinet for anybody in my shop that needs them as well.
I also make sure that my grandkids use PPE when they are working a project here.
My first aid kit is hung on the wall in plain sight.
I wear safety glasses and steel toes shoes in the shop, I got in the habit because of past manufacturing requirements.
I have a box of ear plugs on top of my toolbox, earmuffs, nitrile gloves, leather gloves, quality dust respirator located
on the work bench.
Paint respirator is located with Paint equipment, its stored sealed in a new one-gallon metal paint can.
My welding PPE is stored with my welding equipment.
My biggest risk is chemical absorption through the hands when using paint stripper, pesticides, chemicals and such.
Nitrile is great for grease and oil but not good with lacquer thinner concerning absorption rates.
Work safe!