Most metal buildings you see have WMP-10 insulation....fiberglass with a white facing. However, I've never seen one that hasn't developed problems in 10-15 years with the insulation falling, tearing, etc.
I built two hangar buildings with WMP-10, and would never do so again, partly because of the building codes here in PA. For a heated building, the IECC 2009 energy code requires 1" foam blocks on top of the purlins to provide a thermal break between the purlins and the roof panels, because the traditional way of rolling it on top of the purlins and screwing down the roof resulted in compression of the insulation and a significant heat loss. From the top down there was the roof panel, 3" of unfaced over the purlins, blocks on the purlins, the cavity between the purlins filled with faced insulation, held up with strapping. It was a PITA.
For my 3rd building, I went with insulated metal panels both in the roof and walls. They cost more, but the labor savings was huge, with no struggling with insulation in the wind or rain. The only drawback to the IMPs was needing a suction cup device and telehandler/crane to lift them into place.
Another group that built a hangar went with spray foam, but you have to put a fire retardant over the foam even if covered. It works well enough as insulation, but looks ugly if uncovered. Also, they did it with flex conduit, which means they can't add circuits. If you are going to foam, make sure you put plenty of rigid conduit on the walls so you can pull wires later if needed.