An air over water tank is one way that air gets into a system, but it is not the source of the gurgling. Replacing it with a bladder tank and bleeders will stop your need for repeating the bleeding ritual at least annually, but right now you just need to get the air out, and that's where power flushing comes into play.
It sounds like there's a spot in your system that's higher than where you're bleeding. The bleeder will let out air from behind it, but it won't pull out air from higher spots.
Power flushing works, if the system is valved correctly (if someone skipped some parts when installing it, then it may be difficult or even impossible), so bear with me.
Each loop (zone), should have a drain valve. There should also be a shutoff between that drain and the boiler. Close that one shutoff just past the drain, and leave the automatic fill valve working. Then drain water into a large bucket (or, if you have a hose rated for hot water, that can work too). Water will circulate through the zone to the drain, and makeup water will fill the system. The shut valve will prevent the makeup water from going directly to the drain bypassing the zone. That should blow any pockets of air out the drain. Then after shutting the drain, you can open up that valve.
A word of caution here. Drain valves are not all that reliable. Half the time I open one, I find it no longer shuts. I'd have a spare on hand (with a little pipe dope) just in case that happens. They're cheap, and easy to replace (the water will stop flowing if you turn off the supply).