About electrolysis and hydrogen embrittlement.
From what I have read in this and other threads, everyone is happy about the electrolysis method of removing rust, but no one has mentioned anything about a "little" detail called
hydrogen embrittlement. There are a few ways for hydrogen to get into steel and one of them is electrolysis. One article about this subject mentions that hydrogen, which in this case is introduced in the metal when doing the electrolysis derusting, can
"greatly amplify the stress of applied forces within the basis metal which can produce catastrophic fracture at loadings much lower than the typical yield strenght of the material. Hardened steels are particularly susceptible to this phenomena..." It also mentions that hydrogen is easily removed from the metal by baking it immediately after the process that introduced the hydrogen into the metal. A typical baking cycle is to bake at 375 F for 4 hours. There are many other articles about hydrogen embrittlement that mention the same thing about baking the metal part for a few hours.
So I am guessing that everyone may be missing one final step when using electrolysis. Maybe in the case of vises it is not important to bake the vise afterwards, maybe the weakening of the metal is not significant but, at least it is good to know that such a thing as hydrogen embrittlement exist and that it is taken seriously by the metal industry and metal processors. Below is just one of the many articles about this subject.
http://www.artisticplating.net/Hydrogen-Embrittlement-Baking.php
Another article about hydrogen embrittlement:
http://corrosion-doctors.org/Forms-HIC/embrittlement.htm
I have found that most articles about electrolysis derusting itself, written by do-it-yourselvers, do not mention the fact about hydrogen embrittlement. I am guessing they simply do not know about this.
