2 or 3” Dow board can be bought for less than half cost from places that reroof large commercial/industrial buildings. I don’t know whom you have local as I am in Indiana but I know there are some in the northeast. The foam I bought was 3” and was nearly flawless/new looking. They had some that was more beat up but would do quite nice under a slab still.
You can use 1/2” pex for the floor still. Length limit is 250’ on 1/2 so one loop should be to the end of the building and back. Spacing for 1/2” should be 8-12” depend on insulation levels of the walls/ceiling. If you layout you tubing carefully and keep each loop exactly the same length you can save significant money as you won’t need manifold with balancing valves on each loop. A building that size I would place 2 or 3 separate manifold spaced out for the loops to come back to.
Use the expanding propex system with pex A oxygen barrier tubing. It doesn’t restrict flow like crimp fittings, is more leak proof and if linked a heat gun can work it out unlike pex b or c which has to be spliced.
I highly recommend this text book for designing systems. It’s a college text book and can be dry but has all the math. “Modern hydronic heating” isbn 0-8273-6595-0. This is an older edition which is fine. I think I paid 75$ for one but even at 100$ it’s cheap and excellent education. Cover manual j calculations, flow calculations, spacing, layout, and all the different control methods and equipment. Even has a disk with software to do many of these calculations but the older version is 3.5” floppy. I am going to assume the new one is cd rom.
As far as radiantcompany, imho they are hacks. If that offends some I am sorry but their preassemble set ups are over price for the quality they are, and any company that pimps open systems should be though of as hacks. I was going to go with them at first as their marketing/information the have looks good but as I was educated by the above book I realized the many faults with their setups.
Spray Closed cell foam absolutely will absorb water in contact with the ground or other wet locations. I have witnessed it absorb water (although much less than open cell)even in roofs/walls and in boats where it’s used for flotation. On the other hand I have seen Dow xps used in a floating dock for years and not absorb any appreciable amount.
As with yeltdog I have found supplyhouse the best cost and service. They also sell different grades/brands allowing you to choose the level you want. Ie no one sells American made ward fitting locally any more and the Chinese ones the local stores(big box/contractor supply house/ and mom/pop) pimp are guaranteed to leak