Back on the boiler there are two yellow shut offs. Those might be the end of the loops. Above the circulator. Shut them all off and the water supply to it.
Below these yellow ones there is another pipe coming in as well. Put one there as well. I’m a little shut off crazy but makes life easy. If you can isolate that circulator then when it fails on a freezing day you can change it out in 20 min after grabbing one at hd.
When done you will put a hose on the drain. I put one on my main pipe to circulator. Then with the unit still off you just open the fill valve manually, open one zone valve manually, and the shutoff so city water pressure runs through and purges the air out of the zone. Then shut all of that off and repeat with other zones. Not much air will be in system after that.
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