You can sheet it while on the slab. But before you do, sit down with a pencil and some paper and figure out the stud location and build the wall in three sections. You can build them in 12' sections, 10' sections, or even 4 8' sections. But you want to make sure that you have the correct stud spacing (16") and have the sheeting from one section to overlap over to the next section to tie the sections together. Nothing wrong with having two studs side by side, but you want to overlap for strength. When I do it that way, I make sure I overlap to the stud that is 16" away from the end. Doing it this way will allow you to do most of the erecting by yourself.
Ideally though, if you want to do it on the ground, you can frame the wall, sheet it, then have a few bud's over to help you stand the wall or sections up. No way would I (me) attempt to do a complete 32' wall, but two 16' sections wouldn't be too bad.